Journal of Chemical Thermodynamics, Vol.36, No.11, 977-982, 2004
A reformulation of the fundamental thermodynamics of surface tension for spherical bubbles and drops
The surface energy term is revised in classical thermodynamic theory of surface tension for drops and bubbles. This simplifies the resulting analysis and leads immediately to Kelvin's formula for the over-pressure The reformulation turns on interpreting the area element dA not as an element of a fixed area but as the increase due to a growth in bubble or drop size. (C) 2004 Elsevier Ltd. All rights reserved.