Journal of Vacuum Science & Technology B, Vol.22, No.6, 2987-2991, 2004
Conductive nanostructure fabrication by focused ion beam direct-writing of silver nanoparticles
A focused ion beam has been used to directly pattern thin films of organometallic silver nanoparticles down to a resolution of 100 nm. The unexposed regions were washed in hexane leaving the desired pattern, and subsequent annealing formed conductive. metallic features. Multiple-layer structures were also fabricated by spin-coating and exposing additional films of silver nanoparticles on top of already patterned structures. The sensitivity of the nanoparticles to 30 keV Ga+ ions was measured to be approximately 5 muC/cm(2) . Using this technique test structures were fabricated in two and three dimensions with resistivities as low as 288 muOmega cm and 13 muOmega cm for single- and multiple-layer structures, respectively, as compared to a value of 1.589 muOmega cm for bulk silver. To our knowledge, this is the highest demonstrated throughput for any electron or ion beam direct-write process utilizing metal-orgoanic precursors. (C) 2004 American Vacuum Society.