Chemical Engineering Communications, Vol.145, 195-211, 1996
Recirculating reactor for the study of multiphase kinetics
A new laboratory reactor was set up to measure kinetic coefficients in a solid (catalyst)-liquid-gas reacting system.The reactor consists of two parts : an absorber, where the liquid is partially saturated by the gas reactant and a reacting zone, where the liquid alone, containing the dissolved gas, flows through a fixed bed of catalyst.The ricircle of the liquid in the absorber maintains a high concentration of the gas reactant in the liquid also in the zone of reaction, allowing the use of a high mass of catalyst (significative from a statistical point of view) and the achievement of sufficiently high conversion.The tested reaction is the catalysed hydrogenation of alpha-metylstyrene : in order to consider a drastic situation and to verify the results with the literature data, the experimental conditions examined corresponded to very high chemical reaction rate (instantaneous reaction) at the surface of the pellets.The tests were carried out with the reactor working both in batchwise and in continuous operative mode (steady state); the results show the reliability of the new reactor above all when the steady state operation is considered. For the use of the reactor in batchwise condition, the accumulation of the product inside the catalyst particles must be considered for an accurate measurement of the kinetic parameters.