Direct contact membrane distillation (MD) by means of composite membranes with a PVA/PEG hydrophilic layer on a hydrophobic PVDF substrate has been developed for desalination. The effects of brine temperature, salt concentration, running time and the addition of ethanol on the flux of composite membranes have been investigated. Results showed that the flux of the composite membrane did not deteriorate by adopting an additional hydrophilic membrane although durability was obviously improved. More than 99% of the separation coefficient in one run was achieved with the conductivity of the produced fresh water in the range of 6-10 mus/cm. The flux of the composite membrane retained 91% flux of substrate at 70degreesC, being 23.7 kg/h(.)m(2). When the brine temperature rose to 70degreesC, the composite membrane showed a declined concentration polarisation, with a smaller C-mb/C-b (3.89) than that of the substrate (5.79). Although the flux decreased with the increase of brine concentration, it retained 64% flux of pure water at brine solution containing 20% NaCl and was kept almost constant until 25% NaCl. In the continuous running experiments, there was no obvious drop of flux, even after adding 25% ethanol to the brine and running overnight. It is expected that adopting a hydrophilic layer can prohibit the wetting problem that faced traditional MD with hydrophobic membranes.