Fluid Phase Equilibria, Vol.227, No.1, 135-143, 2005
(Solid plus liquid) phase equilibria of binary mixtures containing N-methyl-2-pyrrolidinone and ethers at atmospheric pressure
Solid-liquid equilibria (SLE), have been measured from 270 K to the boiling temperature of the solvent for 10 binary mixtures of N-methyl-2-pyrrolidinone, with ethers (dipropyl ether, dibutyl ether, dipentyl ether, methyl 1,1-dimethylethyl ether, methyl 1,1-dimethylpropyl ether, ethyl 1,1-dimethylpropyl ether, 1,4-dioxane, tetrahydrofuran, tetrahydropyran, 18-crown-6) using a dynamic method. The solubility of N-methyl-2-pyrrolidinone in ethers is lower than in alcohols and generally decreases with an increase of the number of carbon atoms of ether chain. The highest intermolecular solute-solvent interaction is observed for the cyclic ethers and for methyl 1,1-dimethylethyl ether. Experimental solubility results are compared with values calculated by means of the Wilson, UNIQUAC ASM and two NRTL equations utilizing parameters derived from SLE results. The existence of a solid-solid first-order phase transition in 18-crown-6 ether has been taken into consideration in the calculations. The correlation of the solubility data has been obtained with the average root-mean-square deviation of temperature sigma(T) = 0.9 K with UNIQUAC ASM and two NRTL equations and 0.6 K with the Wilson equation. (C) 2004 Elsevier B.V. All rights reserved.
Keywords:experimental solid-liquid equilibria;NMP plus ether mixtures;molecular interactions;correlation