화학공학소재연구정보센터
Chemical Engineering Communications, Vol.176, 175-193, 1999
Estimation of transport properties of liquids
Based on the theory of intermolecular forces and the Hildebrand relation, a generalized equation in terms of refractive index is proposed to estimate viscosity, thermal conductivity and diffusion coefficients of liquid non-polar compounds at various temperatures. Analytical equations are provided to estimate transport properties of n-alkanes in terms of molecular weight. Average deviations for all three properties of various hydrocarbons from C-5 to C-20 are within 1% for a large number of data points. The proposed equation also predicts transport properties of some polar compounds with a reasonable degree of accuracy.