Chinese Journal of Chemical Engineering, Vol.13, No.1, 118-123, 2005
Simple hydrostatic model of contact angle hysteresis of a sessile drop on rough surface
The phenomenon of hysteresis of contact angle is an important topic subject to a long time of argument. A simple hydrostatic model of sessile drops under the gravity in combination with an ideal surface roughness model is used to interpret the process of drop volume increase or decrease of a planar sessile drop and to shed light on the contact angle hysteresis and its relationship with the solid surface roughness. With this model, the advancing and receding contact angles are conceptually explained in terms of equilibrium contact angle and surface roughness only, without invoking the thermodynamic multiplicity. The model is found to be qualitatively consistent to experimental observations on contact angle hysteresis and it suggests a possible way to approach the hysteresis of three-dimensional sessile drops.