Ultrasonic wave propagation, dynamic mechanical analysis, and dielectric analysis were used to monitor relaxation phenomena during the nonisothermal postcure of unsaturated polyester networks. The measurements covered 6 decades of frequency. As a result, the residual reactive groups, immobilized in the glassy state by vitrification during an isothermal cure step, gained molecular mobility, which promoted the formation of additional crosslinks. After the postcure, the reaction was complete, and the maximum achievable glass-transition temperature was reached. Moreover, the frequency and temperature dependence of the two relaxations, one related to the glass-transition temperature of the partially cured sample and the other to the glass transition of the fully cured sample, was evaluated. The Williams-Landel-Ferry equation was used to model the frequency dependence of the main alpha-relaxation data obtained with the different techniques. (C) 2005 Wiley Periodicals, Inc.