Thin Solid Films, Vol.478, No.1-2, 109-115, 2005
Properties of aluminum titanate films prepared by chemical vapor deposition under different aluminum butoxide inputs
Properties of amorphous aluminum titanate films prepared by low-pressure chemical vapor deposition using a mixture of aluminum tri-sec-butoxide, titanium tetrachloride, CO2, and H-2, have been investigated. The higher compressive internal stress is attributed to the films with a thinner thickness. The scratch resistance of the film is strongly related to the internal stress. Some 350 degrees C-deposited films have a defected structure with high dielectric constants of 230-320. Resistivity above 10(11) Omega cm can be obtained for the as-deposited films. Breakdown voltages increase slightly with substrate temperature and were in the range of 1.6-4.9 MV/cm. Refractive indices are in the range of 1.71-2.20. Annealing does not improve the dielectric and electrical properties. Optical transmittance and its spectral modulation are strongly related to the film thickness. (c) 2004 Elsevier B.V. All rights reserved.
Keywords:chemical vapor deposition;electrical properties and measurements;dielectric properties;optical properties