Chemical polishing or electropolishing, instead of mechanical polishing, are recommended for the attainment of metallic surface polishes without the introduction of contaminants or tensions in the surface layers of the metal. The fundamental difference between the chemical and electrochemical polishing processes is that in the latter anodic currents/potentials are used to help in the dissolution and passivation of the metal. In this paper, the use of an oxidizing electrolytic solution (2.5 mol L-1 CrO3 + 5.0 mol L-1 H2SO4) originally employed in electrochemical coloration processes is reported for the electropolishing of AISI-314 stainless steel. Parameters involved in this electropolishing process, such as temperature. current density and time, were optimized so as to attain the best possible results evaluated by the obtained surface brightness measured by reflectance spectra. Surface analyses by scanning electron microscopy allowed a clear correlation between obtained brightness and surface smoothing. The best conditions obtained for the electropolishing process are: temperature of 45 degrees C, electrolysis time of 10 min and current density of around 25 A dm(-2). It should be pointed out that an electropolishing process signature (periodic oscillations of the cell potential) was established; this may be an important tool for optimizing and monitoring electropolishing processes. (c) 2004 Elsevier Ltd. All rights reserved.