Three p.f. flames have been studied in a semi-industrial furnace, using different fuels: a bituminous coal, a lignite, and a biomass (oak sawdust). The operating conditions were exactly the same for the two coals, and very similar to those for the biornass flame. The objective of the Study was to evaluate the impact of differences in fuel composition on flame characteristics, through measurement of the spatial distribution of the main parameters: temperature and concentrations of O-2, CO, NOx, unburnt hydrocarbons, and N2O. The higher volatiles content in the lignite leads to higher temperatures and more intense combustion than the bituminous coal. Nevertheless, as might be expected, more marked differences are observed between the flames from the biomass and coals. The much higher volatiles content of the wood results in a more intense flame close to the burner, as indicated by visual observations and by concentrations of unburnt gases (CO and unburnt hydrocarbons) in that zone. It is remarkable that the combustion zone extends further for the biomass; while unburnt species were very low for the coals at an axial distance of 1 m, high values were detected for the pulverized oak. The measurements suggest that two stages can be distinauished in the biomass flame: a zone of intense combustion close to the burner, followed by a second region where the large biomass particles gradually devolatilize and are consumed. 2005 The Combustion Institute. Published by Elsevier Inc. All rights reserved.