잔류성 유기오염물질 Polychlorinated Biphenyls(PCBs) 분해 처리 기술 현황

이상훈; 서봉국; Sang-Hoon Lee; Bongkuk Sea

Clean Technology, Vol.11, No.1, 29-39, March, 2005

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잔류성 유기오염물질 Polychlorinated Biphenyls(PCBs) 분해 처리 기술 현황

The State-of-the-Art on Technologies for Treatment of Polychlorinated Biphenyls(PCBs) Pollutants

이상훈^†, 서봉국 ¹

연세대학교 CT(청정기술)연구단
¹한국화학연구원 응용화학연구부

Sang-Hoon Lee^†, and Bongkuk Sea¹

Yonsei Center for Clean Technology, Yonsei University, Seoul 120-749, Korea
¹Division of Applied Chemistry, Korea Research Institute of Chemical Technology, Daejeon 305-600, Korea

E-mail:

초록

잔류성 유기오염 물질 (POPs) 중의 하나인 polychlorinated biphenyls (PCBs)는 강한 독성 및 난분해성으로 암, 내분기계장애(환경호르몬) 등을 유발할 수 있는데, 대부분의 PCBs는 변압기, 콘덴서 같은 전기 설비의 절연유를 오염시키고 있다. 국내외의 PCBs 관련 오염 현황 및 관련 대책을 살펴보고, PCBs를 무해화 분해 처리하기 위한 기술로서 소각, 화학적 탈염소, 광화학, 생물학적 처리를 중심으로 국내외 기술 현황 비교 평가 및 특허 출원 동향을 분석하였다. 이를 바탕으로 향후 국내 PCBs 기술 개발 및 대응 방향과 전망을 기술하였다.

Polychlorinated biphenyls, (PCBs) are a group of highly toxic chlorinated industrial chemicals used as dielectrics, coolants and lubricants in electrical transformers. This article reviewed the state-of-the-art on technologies for decomposition of Polychlorinated biphenyls (PCBs), one of the persistent organic materials (POPs). The purpose of this study was to evaluate the feasibility of decontaminating PCBs contaminated pollutants using treatment technologies such as chemical dechlorination, photodegradation and biological transformation.

Keywords:Polychlorinated biphenyls (PCBs);Transformer insulating oils;Dechlorination;Persistence organic pollutants (Pops)

[References]

Lu YL, Giesy JP, Chemosphere, 60, 729 (2005)
Weinberg J, Pops Handbooks for the United Nations Convention on Persistent Organic Pollutants, The International POPs Elimination Network (IPEN) (Sep. 2001)
박정규, 이희선, 잔류성 유기오염물질의 관리현황과 대응방향, 한국환경정책평가연구원(KEI) (Dec. 2000)
Chou SFJ, Griffin RA, "PCBs and the environment", volumeⅠ, pp.101-118 (1992). - PCB 물성 data table
Mes J, Davies DJ, Turton D, Bull. Environ. Contam. Toxicol., 28, 97 (1982)
Safe S, Crit. Rev. Toxicol., 13, 319 (1984)
Fiedler H, "Polychlorinated Biphenyls (PCBs): Uses and Environmental Releases", Proceedings of the Subregional Awareness Raising Workshop on Persistent Organic Pollutants (POPs). St. Petersburg, Russian Federation, 1-4 July (1997)
Safe S, Crit. Rev. Toxicol., 21, 51 (1990)
Ahlborg UG, Chemosphere, 28, 1049 (1994)
Endou K, Kankyokanri, 39, 40 (2003)
Kobayashi T, Kogyozairyo, 49, 51 (2001)
한국기술거래소 : “나트륨 기술 : 폐변압기 중의 PCB 분해기술”, pp.5-8 (2003)
Siegman JR, U.S. Patent, 4910353 (1990)
Felip E, Chemosphere, 33, 2263 (1996)
Furusawa Y, Nagarajan V, Tanokura M, Masai E, Fukuda M, Senda T, J. Mol. Biol., 342, 1041 (2004)
신희덕, “기술동향분석보고서: Vacuum Thermal Recycle의 최근 동향”, 한국과학기술정보연구원 (KISTI) pp.9-11 (2002, 10)

[Related Articles]

[1] Lu YL, Giesy JP, Chemosphere, 60, 729 (2005)

[2] Weinberg J, Pops Handbooks for the United Nations Convention on Persistent Organic Pollutants, The International POPs Elimination Network (IPEN) (Sep. 2001)

[3] 박정규, 이희선, 잔류성 유기오염물질의 관리현황과 대응방향, 한국환경정책평가연구원(KEI) (Dec. 2000)

[4] Chou SFJ, Griffin RA, "PCBs and the environment", volumeⅠ, pp.101-118 (1992). - PCB 물성 data table

[5] Mes J, Davies DJ, Turton D, Bull. Environ. Contam. Toxicol., 28, 97 (1982)

[6] Safe S, Crit. Rev. Toxicol., 13, 319 (1984)

[7] Fiedler H, "Polychlorinated Biphenyls (PCBs): Uses and Environmental Releases", Proceedings of the Subregional Awareness Raising Workshop on Persistent Organic Pollutants (POPs). St. Petersburg, Russian Federation, 1-4 July (1997)

[8] Safe S, Crit. Rev. Toxicol., 21, 51 (1990)

[9] Ahlborg UG, Chemosphere, 28, 1049 (1994)

[10] Endou K, Kankyokanri, 39, 40 (2003)

[11] Kobayashi T, Kogyozairyo, 49, 51 (2001)

[12] 한국기술거래소 : “나트륨 기술 : 폐변압기 중의 PCB 분해기술”, pp.5-8 (2003)

[13] Siegman JR, U.S. Patent, 4910353 (1990)

[14] Felip E, Chemosphere, 33, 2263 (1996)

[15] Furusawa Y, Nagarajan V, Tanokura M, Masai E, Fukuda M, Senda T, J. Mol. Biol., 342, 1041 (2004)

[16] 신희덕, “기술동향분석보고서: Vacuum Thermal Recycle의 최근 동향”, 한국과학기술정보연구원 (KISTI) pp.9-11 (2002, 10)