화학공학소재연구정보센터
Journal of Physical Chemistry B, Vol.109, No.21, 10557-10560, 2005
Growth of conical carbon nanotubes by chemical reduction of M9CO3
Carbon nanotubes were synthesized by chemical reduction of magnesium carbonate with metallic lithium at 600 degrees C. The nanotubes with an average length of 13 mu m and diameter of 60 mn are made of short coaxial conical cylinder tubular graphite sheets with their cone axis parallel to the tube axis, different from the ordinary carbon nanotubes, composed of concentric cylindrical graphite layers with their normal perpendicular to the tube axis. It is suggested that nanoscale rough surface of lithium formed at the interface between supercritical carbon dioxide and liquid lithium takes the roles of both the reductant for reduction of carbon dioxide to carbon and the template for growth of carbon nanotubes.