Inorganic Chemistry, Vol.44, No.12, 4142-4144, 2005
Crystal structure and luminescence of lanthanide monodentate complexes [Ln(C4N4H6O)(2)(H2O)(6)]Cl-3 and [Ln(C4N4H6O)(2)(H2O)(3)(NO3)(3)] (Ln = Tb or Eu)
New eight- and nine-coordinate luminescent europium(III) and terbium(III) complexes 1-4 with carbonyl group coordination have been prepared using the monodentate ligand (L) 2,4-diamino-6hydroxy pyrimidine and characterized by X-ray and spectroscopic methods.