화학공학소재연구정보센터
Journal of Colloid and Interface Science, Vol.291, No.1, 223-228, 2005
Adsorption of fluids in slitlike pores containing a small amount of mobile ions
We apply density functional theory to investigate changes in the phase behavior of a fluid caused by the presence of mobile ions inside the pore. The approach has been based on the fundamental measure density functional theory and on the theory of nonuniform electrolytes developed recently by O. Pizio, A. Patrykiejew, S. Sokolowski [J. Chem. Phys. 121 (2005) 11,957]. We have evaluated capillary condensation phase diagrams for pores of different widths and for different concentrations of confined ions. The calculations have demonstrated that the presence of ions leads to lowering the critical temperature and to an increase of the value of the chemical potential at the capillary condensation point. (c) 2005 Elsevier Inc. All rights reserved.