화학공학소재연구정보센터
Polymer, Vol.46, No.20, 8790-8795, 2005
Power law and scaling for molecular weight dependence of crystal growth rate in polymeric materials
The molecular weight (M) dependence of the linear crystal growth rate (G) and the influence of the super-cooling on the relationship between M and G were studied. The molecular weight dependence of G has been expressed generally as G proportional to M-alpha at a given super-cooling. The temperature dependence of G shows a bell shape with the maximum growth rate (G(max)). The value of alpha was -0.5 at the temperature (T-cmax) of G(max). However, the small super-cooling and the small molecular weight gave a large negative value of alpha. In other words, the value of alpha was dependent not only on the degree of super-cooling (AT) but also on the molecular weight. The effect on alpha by these two factors (Delta T and M) goes off to zero at T-cmax and alpha yields to -0.5. G(max) can be defined as a characteristic intrinsic value to the crystal growth behavior. The molecular weight dependence of G(max) was scaled and expressed as a -0.5 power to molecular weight for all crystalline polymers. (c) 2005 Elsevier Ltd. All rights reserved.