The fluid dynamics of geometries for liquid state materials characterization in microfluidic devices are investigated. Numerical simulation together with flow classification criteria are used to explore combinations of geometry and boundary conditions for which the flow type can be adjusted between simple shear and extension, while providing adequate flow strength and a stable environment for material observation. Two classes of flow geometries are identified. Both make use of opposing, laterally offset fluid streams that produce a stagnation point in the center of the geometry. In the first class, the flow type is manipulated by changing parameters inherent to the base geometry. This first case serves as a basis for identifying a second class in which the flow type is manipulated by changing the pressure boundary conditions, while keeping the geometry constant.