화학공학소재연구정보센터
Chemical Engineering Journal, Vol.111, No.2-3, 225-236, 2005
Permeability-porosity relationship from a geometrical model of shrinking and lattice Boltzmann and Monte Carlo simulations of flow in two-dimensional pore networks
For a broad range of applications, the most important transport property of porous media is permeability. Here we calculate the permeability of pore network approximations of porous media as simple diagenetic or shrinking processes reduces their pore spaces. We use a simple random bond-shrinkage mechanism by which porosity is decreased; a tube is selected at random and its radius is reduced by a fixed factor, the process is repeated until porosity is reduced either to zero or a preset value. For flow simulations at selected porosity levels, we use precise Monte Carlo calculations and the lattice Boltzmann method with a 9-speed model on two-dimensional square lattices. Calculations show a simple power-law behavior, k proportional to phi(m), where k is the permeability and phi the porosity. The value of m relates strongly to the shrinking process and extension, and hence to the skewness of the pore size distribution, which varies with shrinking, and weakly to pore sizes and shapes. Smooth shrinking produces pore space microstructures resembling the starting primitive material; one value of m suffices to describe k versus phi for any value of porosity. Severe shrinking however produces pore space microstructures that apparently forget their origin; the k-phi curve is only piecewise continuous, different values of m are needed to describe it in the various porosity intervals characterizing the material. The power-law thus is not universal, a well-known fact. An effective pore length or critical pore size parameter, 1, characterizes pore space microstructures at any level of porosity. For severe shrinking 1, becomes singular, indicating a change in the microstructure controlling permeability, and thus flow, thus explaining k-phi power-law transitions. Continuation of the various k-phi pieces down to zero permeability reveals pseudo-percolation thresholds phi'(c) for the porosity of the controlling microstructures. New graphical representations of k/l(2)(c) versus phi -phi'(c) for the various phi intervals display straight and parallel lines, with a slope of 1. Our results confirm that a universal relationship between k/l(c)(2) and phi should not be discarded. (c) 2005 Published by Elsevier B.V.