Journal of Colloid and Interface Science, Vol.294, No.1, 38-46, 2006
Sub-monolayer growth by sequential deposition of particles
We studied the various stages in the preparation of a sub-monolayer film by the sequential deposition of particles (sequential quenching model) from very low to very high temperatures, a limit at which the system becomes equivalent to random sequential adsorption. Due to the finite size of the simulation box, only one cluster can be found in a system at very low temperatures (T* = 0.01 and 0.1) and its size grows linearly with increasing density. At higher temperatures (T* = 0.3 or higher), on the other hand, the same systems show a crossover from a nucleation regime to a growth regime. It is best revealed in a plot showing the distribution of monomers on the surface versus density, where the crossover region appears as a peak on a curve. At densities above the crossover, any new addition tends to contribute to the growth of an existing cluster rather than to nucleating new one. (c) 2005 Elsevier Inc. All rights reserved.
Keywords:non-equilibrium growth;irreversible adsorption;sequential deposition;random sequential adsorption