Chemical Engineering Science, Vol.49, No.13, 2075-2087, 1994
Induction Phenomena in Gas Hydrate Nucleation
The induction phenomena in hydrate nucleation have been investigated experimentally and the induction period data are reported for methane, ethane and carbon dioxide hydrates. Based on crystallization considerations, the metastable region for hydrate nucleation is discussed and the driving force for hydrate nucleation is defined. The induction period data for the various hydrates from a total of 93 hydrate formation runs were modelled as a function of the nucleation driving force.
Keywords:AQUEOUS-ELECTROLYTE SOLUTIONS;TREBBLE-BISHNOI EQUATION;EQUILIBRIUM CONDITIONS;MOLECULAR-DYNAMICS;METHANE;ETHANE;WATER;KINETICS;SYSTEMS;PREDICTION