A series of poly[omega-(4'-methoxy-biphenyl-4-oxy)alkyl-1-glycidylether]s were synthesized by chemically modifying the corresponding poly(omega-bromoalkyl-1-glycidyl-ether)s with the sodium salt of 4-hydroxy-4'-methoxybiphenyl. New high-molecular-weight side-chain liquid-crystalline polymers were obtained with excellent yields and almost quantitative degrees of modification. They were all insoluble in THF and other common solvents. Characterization by C-13 NMR confirmed that all the polymers had the expected structure. The liquid crystalline behavior of the polymers was analyzed by DSC and polarized optical microscopy, and mesophase assignments were confirmed by X-ray diffraction studies. Polymers that had alkyl spacers with n = 2 and 4 were smectic C, those that had spacers with n = 6 and 8 were nematic cybotactic, and those that had longer spacers (n = 10 and 12) were smectic C again. (c) 2005 Wiley Periodicals, Inc.