Mixing properties of propyl acetate+aromatic hydrocarbons at 298.15K

Jos´e M. Resa; Cristina Gonz´alez; Soraya Prieto; Elena D´iez; Miguel Iglesias

Korean Journal of Chemical Engineering, Vol.23, No.1, 93-101, January, 2006

DOI10.1007/BF02705698 Export Citation

Mixing properties of propyl acetate+aromatic hydrocarbons at 298.15K

Jos´e M. Resa^†, Cristina Gonz´alez, Soraya Prieto, Elena D´iez, and Miguel Iglesias

Dpto. de Ingenieria Qu´imica, Universidad del Pais Vasco, Apto. 450, Vitoria, Spain

E-mail:

We present experimental data of speed of sound, refractive index on mixing and density for the binaries of propyl acetate+(toluene, ethylbenzene, p-xylene, isopropylbenzene, butylbenzene, isobutylbenzene, mesitylene, or t-butylbenzene) at T=298.15 K and 1 atm, and the corresponding computed derived magnitudes (change of isentropic compressibility, change of refractive index on mixing, and excess molar volume). The mixtures show a clear expansive tendency for the highest molar weight compounds, and the steric hindrance role of the aromatic chemicals was analyzed to the light of the non ideality on mixing. Values of physical properties were compared with the results obtained by theoretical estimation procedures.

Keywords:Excess Volumes;Change of Refractive Indices;Change of Isentropic Compressibility;Propyl Acetate;Aromatic Hydrocarbon;Estimation

[References]

Bevington P, Data reduction and error analysis for the physical sciences, McGraw-Hill, New York (1969)
Kay WE, J. Ind. Eng. Chem., 28, 1014 (1936)
Iglesias M, Orge B, Tojo J, Fluid Phase Equilib., 126(2), 203 (1996)
Nutsch-kuhnkies R, Acustica, 15(1), 383 (1965)
Prausnitz JM, Gunn RD, AIChE J., 4, 430 (1958)
Qin A, Hoffman DE, Munk P, J. Chem. Eng. Data, 37, 66 (1992)
Redlich O, Kister AT, Ind. Eng. Chem., 40, 345 (1948)
Reid RC, Prausnitz JM, Poling BE, The properties of gases and liquids, 5th ed., McGraw-Hill, Singapore (1988)
Resa JM, Gonzalez C, Lanz J, Mtz. de Ilarduya JA, J. Therm. Anal. Calorim., 52(3), 895 (1998)
Resa JM, Iglesias M, Gonzalez C, Lanz J, de Ilarduya JAM, J. Chem. Thermodyn., 33(7), 723 (2001)
Resa JM, Gonzalez C, de Landaluce O, Lanz J, J. Chem. Thermodyn., 34(7), 995 (2002)
Riddick JA, Bunger WB, Sakano TK, Organic solvents, Wiley-Interscience, USA (1986)
Schaaffs W, Acustica, 33(4), 272 (1975)
Spencer CF, Danner RP, J. Chem. Eng. Data, 17(2), 236 (1972)
TRC thermodynamic tables, Thermodynamic Research Center, Texas A&M University: College Station, TX (1994)

[Referenced By]

[1] Bevington P, Data reduction and error analysis for the physical sciences, McGraw-Hill, New York (1969)

[2] Kay WE, J. Ind. Eng. Chem., 28, 1014 (1936)

[3] Iglesias M, Orge B, Tojo J, Fluid Phase Equilib., 126(2), 203 (1996)

[4] Nutsch-kuhnkies R, Acustica, 15(1), 383 (1965)

[5] Prausnitz JM, Gunn RD, AIChE J., 4, 430 (1958)

[6] Qin A, Hoffman DE, Munk P, J. Chem. Eng. Data, 37, 66 (1992)

[7] Redlich O, Kister AT, Ind. Eng. Chem., 40, 345 (1948)

[8] Reid RC, Prausnitz JM, Poling BE, The properties of gases and liquids, 5th ed., McGraw-Hill, Singapore (1988)

[9] Resa JM, Gonzalez C, Lanz J, Mtz. de Ilarduya JA, J. Therm. Anal. Calorim., 52(3), 895 (1998)

[10] Resa JM, Iglesias M, Gonzalez C, Lanz J, de Ilarduya JAM, J. Chem. Thermodyn., 33(7), 723 (2001)

[11] Resa JM, Gonzalez C, de Landaluce O, Lanz J, J. Chem. Thermodyn., 34(7), 995 (2002)

[12] Riddick JA, Bunger WB, Sakano TK, Organic solvents, Wiley-Interscience, USA (1986)

[13] Schaaffs W, Acustica, 33(4), 272 (1975)

[14] Spencer CF, Danner RP, J. Chem. Eng. Data, 17(2), 236 (1972)

[15] TRC thermodynamic tables, Thermodynamic Research Center, Texas A&M University: College Station, TX (1994)