Polymer, Vol.46, No.25, 11451-11462, 2005
Bulk free radical polymerizations of methyl methacrylate under non-isothermal conditions and with intermediate addition of initiator: Experiments and modeling
Experimental data on the monomer conversion, x(m), and the weight average molecular weight, M-w, have been generated under several isothermal and non-isothermal conditions for the polymerization of methyl methacrylate in a rheometer-reactor assembly. The non-isothermal results, in particular, can be used to provide more stringent tests of kinetic models than isothermal data alone. A simple empirical model has been used to describe this system that accounts for the gel (Trommsdorff) and glass effects. The model involves only x and the temperature, and is quite general. The model parameters are tuned using only three sets of isothermal data. Good agreement is found between the experimental results and model predictions for a whole variety of experimental condition, including non-isothermal operation and with intermediate addition of initiator. Because of its generality, this model is quite suitable for use for on-line optimizing control as well as for describing industrial reactors. (c) 2005 Published by Elsevier Ltd.