화학공학소재연구정보센터
Rheologica Acta, Vol.45, No.3, 297-304, 2006
Strain recovery of model immiscible blends without compatibilizer
Strain recovery after the cessation of shear was studied in model immiscible blends composed of polyisobutylene drops (10-30% by weight) in a polydimethylsiloxane matrix. Blends of viscosity ratio (viscosity of the drops relative to the matrix viscosity) ranging from 0.3 to 1.7 were studied. Most of the strain recovery was attributable to interfacial tension, and could be well-described by just two parameters: the ultimate recovery and a single retardation time. Both these parameters were found to increase with the capillary number of the drops prior to cessation of shear. For blends that had reached steady shear conditions, the ultimate recovery decreased with increasing viscosity ratio, whereas the retardation time increased with increasing viscosity ratio. The retardation time was well-predicted, but the ultimate recovery was over-predicted by a linear viscoelastic model developed previously by Vinckier et al.