Chemical Synthesis of Stabilized Nanocrystalline Zirconia Powders

Jagadish Chandra Ray; Dong-Wha Park; Wha-Seung Ahn

Journal of Industrial and Engineering Chemistry, Vol.12, No.1, 142-148, January, 2006

Export Citation

Chemical Synthesis of Stabilized Nanocrystalline Zirconia Powders

Jagadish Chandra Ray, Dong-Wha Park , and Wha-Seung Ahn^†

Department of Chemical Engineering and the Institute of Clean Technology, Inha University, Incheon 402-751, Korea

E-mail:

Nanocrystalline metastable phases of zirconia can be prepared through a novel chemical method using a polymer-based precursor solution with sucrose, poly(vinyl alcohol), and metal ions. Pyrolysis of the precursor over a hot plate at ca. 250 ℃ followed by calcination at temperatures up to 1200 ℃ resulted in zirconia nanocrystals in the form of a powder. Y3+, Cr3+, Th4+, Ta5+ were used as stabilizing agents. Precursors and powders were characterized using TG-DTA, XRD, and TEM. THetetragonal and cubic phases were stabilizedand the particle sizes of the powders were 20~60 nm having crystallite sizes 5~30 nm.

Keywords:zirconia;nanocrystals;polymer precursor;stabilizing agents

[References]

Hu MZC, Hunt RD, Payzant EA, Hubbard CR, J. Am. Ceram. Soc., 82, 2313 (1999)
Hannink RHJ, Kelly PM, Muddle BC, J. Am. Ceram. Soc., 83, 461 (2000)
Ilyas M, Shah S, Niger R, Khan H, J. Chem. Soc.-Faraday Trans., 90, 2413 (1994)
Li GL, Tatsumi I, Yoshihiko MO, Yusaku T, Appl. Catal. B: Environ., 9(1-4), 239 (1996)
Burkhard DJM, Hanson B, Ulmer GC, Solid State Ion., 47, 169 (1991)
Browall KW, Dorimus RH, J. Am. Ceram. Soc., 60, 262 (1977)
Yokoyama T, Fujita N, Maki T, Appl. Catal. A: Gen., 125(1), 159 (1995)
Sohn JR, Han JS, Lim JS, J. Ind. Eng. Chem., 10(6), 1003 (2004)
Sohn JR, Han JS, J. Ind. Eng. Chem., 11(3), 439 (2005)
Gavie RC, Hannink RHJ, Pascoe RT, Nature, 258, 703 (1975)
Karch J, Birringer R, Gleiter H, Nature, 330, 556 (1987)
Edington JW, Melton KS, Cutler CP, Prog. Mater. Sci., 21, 61 (1976)
Srdic VV, Winterer M, Hahn H, J. Am. Ceram. Soc., 83, 729 (2000)
Birringer R, Herr U, Gleiter H, Suppl. Trans. Jpn. Inst. Met., 27, 43 (1986)
Mishra VV, Grag AK, Agarwal DC, Bull. Mat. Sci., 21, 81 (1998)
Skadan G, Han H, Roddy M, Cannon WR, J. Am. Ceram. Soc., 77, 1706 (1994)
Xia B, Duan L, Xie Y, J. Am. Ceram. Soc., 83, 1077 (2000)
Srinivasan R, Rice L, Davis BH, J. Am. Ceram. Soc., 73, 3528 (1990)
Benedetti A, Faghefazzi G, Pinna F, J. Am. Ceram. Soc., 72, 467 (1989)
Garvie RC, J. Phys. Chem., 69, 1238 (1965)
Inshida K, Hirota K, Yamaguchi O, J. Am. Ceram. Soc., 77, 1391 (1995)
Murase Y, Kato E, Nippon Kagaku Kaishi, 3, 425 (1967)
Tsukada T, Venigalla S, Morrone AA, Adair JH, J. Am. Ceram. Soc., 82, 1169 (1999)
Clearfield A, Voughan PA, Acta Cryst., 9, 555 (1956)
Morgan PED, J. Am. Ceram. Soc., 67, C-204 (1984)
Xiaming D, Quingfeng L, Yuying T, J. Am. Ceram. Soc., 76, 760 (1993)
Stefanic G, Popovic S, Music S, Mater. Lett., 36, 240 (1993)
Xie Y, J. Am. Ceram. Soc., 82, 768 (1999)
Venkatachari KR, Huang D, Ostrander SP, Schulze WA, Stangle GC, J. Mater. Res., 10, 784 (1995)
Zhau E, Bhaduri S, Bahduri SB, Lewis IR, Graffiths PR, Processing and properties of nanocrystalline materials, C. Suryanarayana, J. Singh, and F. H. Froes Eds., pp-123, The Minerals, Metals & Materials Society (1996)
Sahu HR, Rao GR, Bull. Mat. Sci., 23, 349 (2000)
JCPDS: Card No. PDF # 49-1642
Hartridge A, Tylor MD, Bhattacharya AK, J. Mater. Res., 16, 2384 (2001)
del Monte F, Larsen W, Mackenzic JD, J. Am. Ceram. Soc., 83, 1506 (2000)
Garvie RC, J. Phys. Chem., 82, 218 (1978)
Stubical VS, in Advances in Ceramics: Science and Technology in Zirconia III, edited by H. Yanagida, N. Yonamolo, and S. Somiya Eds., Americal Ceramic Society, Columbus OH (1988)
Clearfield A, Inorg. Chem., 3, 146 (1964)
Moulzolf SC, Lad RT, J. Mater. Res., 15, 369 (2000)
JCPDS: Card No. PDF # 24-1164
Smith DK, Cline CF, J. Am. Ceram. Soc., 45, 249 (1962)
Ray JC, Pati RK, Pramanik P, J. European Ceram. Soc., 20, 1289 (2000)
Panda AB, Ray JC, Pramanik P, J. European Ceram. Soc., 23, 3043 (2003)
Ray JC, Panda AB, Pramanik P, Mater. Lett., 53, 145 (2002)
Ray JC, Panda AB, Saha CR, Pramanik P, J. Am. Ceram. Soc., 86, 514 (2003)
Gavie RC, J. Phys. Chem., 69, 1238 (1965)
Ho SM, Mater. Sci. Eng., 54, 23 (1982)
Li P, Chen IW, Penner-Hahn JE, J. Am. Ceram. Soc., 77, 118 (1994)
Kim DJ, Tien TY, J. Am. Ceram. Soc., 74, 3061 (1991)

[Referenced By]

[Related Articles]

[1] Hu MZC, Hunt RD, Payzant EA, Hubbard CR, J. Am. Ceram. Soc., 82, 2313 (1999)

[2] Hannink RHJ, Kelly PM, Muddle BC, J. Am. Ceram. Soc., 83, 461 (2000)

[3] Ilyas M, Shah S, Niger R, Khan H, J. Chem. Soc.-Faraday Trans., 90, 2413 (1994)

[4] Li GL, Tatsumi I, Yoshihiko MO, Yusaku T, Appl. Catal. B: Environ., 9(1-4), 239 (1996)

[5] Burkhard DJM, Hanson B, Ulmer GC, Solid State Ion., 47, 169 (1991)

[6] Browall KW, Dorimus RH, J. Am. Ceram. Soc., 60, 262 (1977)

[7] Yokoyama T, Fujita N, Maki T, Appl. Catal. A: Gen., 125(1), 159 (1995)

[8] Sohn JR, Han JS, Lim JS, J. Ind. Eng. Chem., 10(6), 1003 (2004)

[9] Sohn JR, Han JS, J. Ind. Eng. Chem., 11(3), 439 (2005)

[10] Gavie RC, Hannink RHJ, Pascoe RT, Nature, 258, 703 (1975)

[11] Karch J, Birringer R, Gleiter H, Nature, 330, 556 (1987)

[12] Edington JW, Melton KS, Cutler CP, Prog. Mater. Sci., 21, 61 (1976)

[13] Srdic VV, Winterer M, Hahn H, J. Am. Ceram. Soc., 83, 729 (2000)

[14] Birringer R, Herr U, Gleiter H, Suppl. Trans. Jpn. Inst. Met., 27, 43 (1986)

[15] Mishra VV, Grag AK, Agarwal DC, Bull. Mat. Sci., 21, 81 (1998)

[16] Skadan G, Han H, Roddy M, Cannon WR, J. Am. Ceram. Soc., 77, 1706 (1994)

[17] Xia B, Duan L, Xie Y, J. Am. Ceram. Soc., 83, 1077 (2000)

[18] Srinivasan R, Rice L, Davis BH, J. Am. Ceram. Soc., 73, 3528 (1990)

[19] Benedetti A, Faghefazzi G, Pinna F, J. Am. Ceram. Soc., 72, 467 (1989)

[20] Garvie RC, J. Phys. Chem., 69, 1238 (1965)

[21] Inshida K, Hirota K, Yamaguchi O, J. Am. Ceram. Soc., 77, 1391 (1995)

[22] Murase Y, Kato E, Nippon Kagaku Kaishi, 3, 425 (1967)

[23] Tsukada T, Venigalla S, Morrone AA, Adair JH, J. Am. Ceram. Soc., 82, 1169 (1999)

[24] Clearfield A, Voughan PA, Acta Cryst., 9, 555 (1956)

[25] Morgan PED, J. Am. Ceram. Soc., 67, C-204 (1984)

[26] Xiaming D, Quingfeng L, Yuying T, J. Am. Ceram. Soc., 76, 760 (1993)

[27] Stefanic G, Popovic S, Music S, Mater. Lett., 36, 240 (1993)

[28] Xie Y, J. Am. Ceram. Soc., 82, 768 (1999)

[29] Venkatachari KR, Huang D, Ostrander SP, Schulze WA, Stangle GC, J. Mater. Res., 10, 784 (1995)

[30] Zhau E, Bhaduri S, Bahduri SB, Lewis IR, Graffiths PR, Processing and properties of nanocrystalline materials, C. Suryanarayana, J. Singh, and F. H. Froes Eds., pp-123, The Minerals, Metals & Materials Society (1996)

[31] Sahu HR, Rao GR, Bull. Mat. Sci., 23, 349 (2000)

[32] JCPDS: Card No. PDF # 49-1642

[33] Hartridge A, Tylor MD, Bhattacharya AK, J. Mater. Res., 16, 2384 (2001)

[34] del Monte F, Larsen W, Mackenzic JD, J. Am. Ceram. Soc., 83, 1506 (2000)

[35] Garvie RC, J. Phys. Chem., 82, 218 (1978)

[36] Stubical VS, in Advances in Ceramics: Science and Technology in Zirconia III, edited by H. Yanagida, N. Yonamolo, and S. Somiya Eds., Americal Ceramic Society, Columbus OH (1988)

[37] Clearfield A, Inorg. Chem., 3, 146 (1964)

[38] Moulzolf SC, Lad RT, J. Mater. Res., 15, 369 (2000)

[39] JCPDS: Card No. PDF # 24-1164

[40] Smith DK, Cline CF, J. Am. Ceram. Soc., 45, 249 (1962)

[41] Ray JC, Pati RK, Pramanik P, J. European Ceram. Soc., 20, 1289 (2000)

[42] Panda AB, Ray JC, Pramanik P, J. European Ceram. Soc., 23, 3043 (2003)

[43] Ray JC, Panda AB, Pramanik P, Mater. Lett., 53, 145 (2002)

[44] Ray JC, Panda AB, Saha CR, Pramanik P, J. Am. Ceram. Soc., 86, 514 (2003)

[45] Gavie RC, J. Phys. Chem., 69, 1238 (1965)

[46] Ho SM, Mater. Sci. Eng., 54, 23 (1982)

[47] Li P, Chen IW, Penner-Hahn JE, J. Am. Ceram. Soc., 77, 118 (1994)

[48] Kim DJ, Tien TY, J. Am. Ceram. Soc., 74, 3061 (1991)