A study on the application of UV curing ink with sulfonate type acid amplifier

Mun Hag Lee; Sung Bin Kim; Se Mo Son; Jae Kee Cheon

Korean Journal of Chemical Engineering, Vol.23, No.2, 309-316, March, 2006

DOI10.1007/BF02705733 Export Citation

A study on the application of UV curing ink with sulfonate type acid amplifier

Mun Hag Lee^†, Sung Bin Kim¹, Se Mo Son¹, and Jae Kee Cheon²

Dept. of Image Printing, Incheon City College, Korea
¹Division of Image & Information Engineering, Pukyong Nationl University, Busan 608-739, Korea
²Division of Applied Chemical Engineering, College of Engineering, Pukyong Nationl University, Busan 608-739, Korea

E-mail:

In this paper, both mono-type: 4-hydroxycyclohexyl-4-vinylbenzenesulfonate(CHDv-m), 4-(4-hydroxy-cyclohexyl) cyclohexyl-4-vinylbenzenesulfonate(BCDv-m), 4-(2-(4-hydroxycyclohexyl)propan-2-yl)-cyclohexyl-4-vinyl-benzenesulfonate(IPDHv-m), 4-hydroxycyclohexyl-4-methylbenzenesulfonate(CHDp-m), 4-(4-hydroxycyclohexyl)-cyclo-hexyl-4-methylbenzenesulfonate(BCDp-m) and 4-(2-(4-hydroxycyclohexyl)propan-2-yl)-cyclohexyl-4-methylbenzene-sulfonate(IPDHp-m) and di-type: 4,4'-di(vinylbenzenesulfonatyl)-cyclohexane(CHDv-d), 4,4'-di(vinylbenzenesulfonatyl)-1,1'-bicyclohexane(BCDv-d), 4,4'-di(vinlylbenzenesulfonatyl)-isopropylidene-dicyclohexane(IPDHv-d), 1,4-ditosyloxycyclohexane(CHDp-d), 4,4'-ditosyloxy-1,1'-bicyclohexane(BCDp-d) and 4,4'-ditosyloxy isopropylidene dicyclohexane(IPDHp-d) acid amplifiers were synthesized. Their properties were characterized by 1HNMR and DSC measurements.UV curing properties of samples prepared by using novel acid amplifiers were examined by measuring the change ofcurrent according to UV radiation time and intensity. Also, the application of acid amplifiers to UV inks was suggested.It was found that UV vehicles and inks with acid amplifier of 4-4'di(vinylbenzenesulfonatyl)-cyclohexane(CHDv-d) hada more rapid degree of curing than other samples.

Keywords:UV Ink;UV Curing Process;Acid Amplifier;Acid Amplification

[References]

Chai YS, Lee JC, Kim BW, Korean J. Chem. Eng., 17(6), 633 (2000)
Han JD, Woo SI, Korean J. Chem. Eng., 10(3), 164 (1993)
Jung KT, Shul YG, Anpo M, Yamashita H, Korean J. Chem. Eng., 14(3), 213 (1997)
Kim CK, Chung CH, Moon SH, Korean J. Chem. Eng., 13(3), 328 (1996)
Lee HJ, Kang DW, Chi J, Lee DH, Korean J. Chem. Eng., 20(3), 503 (2003)
Lee JC, Kim MS, Kim CK, Chung CH, Cho SM, Han GY, Yoon KJ, Kim BW, Korean J. Chem. Eng., 20(5), 862 (2003)
Lee MH, Lee TH, Kim SB, Son SM, J. Korean Printing Society, 21-2, 55 (2003)
McKean DR, Schaedeli UP, MacDonald SA, J. Polym. Sci. A: Polym. Chem., 27(12), 3927 (1989)
McKean DR, Schaedeli UP, Kasai PH, MacDonald SA, J. Polym. Sci. A: Polym. Chem., 29(3), 309 (1991)
Na YS, Lee CH, Lee TK, Lee SW, Park YS, Oh YK, Park SH, Song SK, Korean J. Chem. Eng., 22(2), 246 (2005)
Tada S, Serizawa I, Adachi N, Takahashi Y, Bulletin of The Japanese Society of Printing Science and Technology, 32-1, 28 (1995)
Tada S, Takahashi Y, Serisawa I, Adachi N, Bulletin of The Japanese Society of Printing Science and Technology, 33, 307 (1996)
Tada S, Takahashi Y, Serizawa I, Adachi N, Bulletin of The Japanese Society of Printing Science and Technology, 33-5, 16 (1996)
Takahashi Y, Tada S, Yamada S, “Direct evaluation method of UV curing process on the basis of conductivity change of polymerization materials,” IS & T's 50th Annual Conference, 559 (1997)

[Referenced By]

[Related Articles]

[1] Chai YS, Lee JC, Kim BW, Korean J. Chem. Eng., 17(6), 633 (2000)

[2] Han JD, Woo SI, Korean J. Chem. Eng., 10(3), 164 (1993)

[3] Jung KT, Shul YG, Anpo M, Yamashita H, Korean J. Chem. Eng., 14(3), 213 (1997)

[4] Kim CK, Chung CH, Moon SH, Korean J. Chem. Eng., 13(3), 328 (1996)

[5] Lee HJ, Kang DW, Chi J, Lee DH, Korean J. Chem. Eng., 20(3), 503 (2003)

[6] Lee JC, Kim MS, Kim CK, Chung CH, Cho SM, Han GY, Yoon KJ, Kim BW, Korean J. Chem. Eng., 20(5), 862 (2003)

[7] Lee MH, Lee TH, Kim SB, Son SM, J. Korean Printing Society, 21-2, 55 (2003)

[8] McKean DR, Schaedeli UP, MacDonald SA, J. Polym. Sci. A: Polym. Chem., 27(12), 3927 (1989)

[9] McKean DR, Schaedeli UP, Kasai PH, MacDonald SA, J. Polym. Sci. A: Polym. Chem., 29(3), 309 (1991)

[10] Na YS, Lee CH, Lee TK, Lee SW, Park YS, Oh YK, Park SH, Song SK, Korean J. Chem. Eng., 22(2), 246 (2005)

[11] Tada S, Serizawa I, Adachi N, Takahashi Y, Bulletin of The Japanese Society of Printing Science and Technology, 32-1, 28 (1995)

[12] Tada S, Takahashi Y, Serisawa I, Adachi N, Bulletin of The Japanese Society of Printing Science and Technology, 33, 307 (1996)

[13] Tada S, Takahashi Y, Serizawa I, Adachi N, Bulletin of The Japanese Society of Printing Science and Technology, 33-5, 16 (1996)

[14] Takahashi Y, Tada S, Yamada S, “Direct evaluation method of UV curing process on the basis of conductivity change of polymerization materials,” IS & T's 50th Annual Conference, 559 (1997)