The interaction between molecular hydrogen and the alkali-metal-exchanged zeolites Na-FER and K-FER at a low temperature was investigated by combining variable-temperature infrared spectroscopy and theoretical calculations by using a periodic DFT model. The experimentally determined values of standard adsorption enthalpy, Delta H degrees, were -6.0 (+/- 0.8) and -3.5 (+/- 0.8) kJ mol(-1) for Na-FER and K-FER, respectively. These results were found to be in agreement with corresponding Delta H degrees values obtained from calculations on the periodic model. Two types of alkali-metal cation sites in FER were found: channel intersection sites and channel wall sites. Calculations showed a similar interaction energy for both site types, and similar structures of adsorption complexes. Up to two dihydrogen molecules can be physisorbed on the alkali-metal cation located on the intersection of two channels, while only one H-2 molecule is physisorbed on the cation at the channel wall site. The adsorption enthalpies of H-2 on alkali-metal-exchanged FER are significantly smaller than those found previously for the MFI-type zeolites Na-ZSM-5 and K-ZSM-5, which is likely due to a difference in the alkali-metal cation coordination in the two zeolite frameworks.