In an earlier mathematical model of laminar pulverized coal-air combustion, supported by added CH4, it was assumed that the volatiles from the coal consisted solely of CH4 and HCN. A revised model is introduced with speciated devolatilization rate constants for tar, CH4, CO, CO2, H2O, H-2, and HCN. It is assumed that these rate constants can also be applied to the devolatilization of the tar. In addition, it is assumed that the soot is predominantly carbon and is oxidized by the attack of 0, H, OH, and 02, in the same way as the coal char. Because the devolatilization rate is strongly dependent on particle temperature, the latter has to be determined accurately from the momentum and energy equations of the particle. The model is one-dimensional, with axial radiative transfer. The introduction of soot formation and speciation of the volatiles results in much improved accuracy in the prediction of species and temperature profiles in subatmospheric combustion on a flat flame matrix burner. It is possible to derive an overall global devolatilization rate constant that agrees reasonably with the measurements. These computations suggest that the effective area of the assumed spherical coal char particles is four times greater than that of the assumed sphere. Modeling of atmospheric pressure flames suggests that in this case, the value of 4 should. be reduced, probably because, as pressure increases, the diffusion flux of reactant is reduced. Subatmospheric pressure laminar burning velocities are predicted with satisfactory accuracy over the full range of overall equivalence ratios. Previous measurements of laminar burning velocity at atmospheric pressure are reviewed. However, the various means of supporting a stable coal flame and the associated uncertain geometries make it impossible to apply the present model to the different conditions. It is suggested that burning velocities measured on a flat flame burner, with a controlled amount of methane to support the combustion of a pulverized coal/air mixture, would provide a good test of the reactivities of different coals. (c) 2005 The Combustion Institute. Published by Elsevier Inc. All rights reserved.