The curing system of diglycidyl ether of bisphenol A (DGEBA) with two phosphorus-containing amine compounds-bis(3-aminophenyl)methyl phosphine oxide and bis(4-aminophenyl)-bis(9,10-dihydro-9-oxa-10-oxide-10-phosphaphenanthren e-10-yl)methane-was studied with differential scanning calorimetry under isothermal and nonisothermal conditions and compared with the DGEBA/diamino diphenyl methane system. The isoconversional method was used to evaluate the dependence of the effective activation energy on the extent of conversion. Modulated differential scanning calorimetry and dynamic mechanical thermal analysis were used to study the phenomena of vitrification and gelation. The thermal and flame-retardant properties were evaluated, and the limiting oxygen index values of the phosphorylated resins, above 30, confirmed that phosphorus-containing epoxy resins are effective flame retardants. (c) 2006 Wiley Periodicals, Inc.