Langmuir, Vol.22, No.6, 2863-2869, 2006
Primary electroviscous effect in a dilute suspension of charged mercury drops
The standard theory of the primary electroviscous effect in a dilute suspension of charged spherical rigid particles in an electrolyte solution (Watterson, I. G.; White, L. R. J. Chem. Soc., Faraday Trans. 2 1981, 77 1115) is extended to cover the case of a dilute suspension of charged mercury drops Of Viscosity eta(d). A general expression for the effective viscosity or the electroviscous coefficient p of the suspension is derived. This expression tends to that for the case of rigid particles in the limit of eta(d) -> infinity. We also derive an approximate analytical viscosity expressions applicable to mercury drops carrying low zeta potentials at arbitrary kappa alpha (where kappa is the Debye-Huckel parameter and alpha is the drop radius) and to mercury drops as well as rigid spheres with arbitrary zeta potentials at large kappa alpha. It is shown that the large-kappa alpha expression of p for rigid particles predicts a maximum when plotted as a function of zeta potential. This result for rigid particles agrees with the exact numerical results of Watterson and White. It is also shown that in the limit of high zeta potential the effective viscosity of a suspension of mercury drops tends to that of uncharged rigid spheres given by Einstein's formula (Einstein, A. Ann. Phys. 1906, 19, 289), whereas in the opposite limit of low zeta potential the effective viscosity approaches that of a suspension of uncharged liquid drops derived by Taylor (Taylor, G. 1. Proc. R. Soc. London, Ser. A 1932, 138, 41).