배향된 MFI 제올라이트 박막의 제조

송경근; 하광; Kyeong-Keun Song; Kwang Ha

Korean Chemical Engineering Research, Vol.44, No.3, 243-247, June, 2006

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배향된 MFI 제올라이트 박막의 제조

Preparation of Oriented MFI Zeolite Membranes

송경근 , 하광 ^†

전남대학교 응용화학공학부, 500-757 광주시 북구 용봉동 300

Kyeong-Keun Song , and Kwang Ha^†

Faculty of Applied Chemical Engineering, Chonnam National University, 300, Yongbong-dong, Buk-gu, Gwangju 500-757, Korea

E-mail:

초록

Anodic alumina(Anodisc)를 지지체로 사용하여 MFI 제올라이트 박막을 제조하였다. 먼저 화학결합을 이용하여 지지체에다 silicalite-1 종자 결정(c-축 길이 1.2 μm)을 결합시켰고, 제올라이트 단층막으로 덮인 지지체 위에 이차성장 수열합성법을 사용하여 결정들이 a-축과 b-축으로만 배향된 제올라이트 박막을 형성하였다. 제조된 박막은 주사형 전자현미경으로 관찰하였고, X-ray 회절로 분석하였다.

MFI zeolite membranes were prepared on anodic alumina (Anodisc) as support. First, silicalite-1 (≒1.2 μm) seed crystals were attached to the surface of the support via chemical bonding, and the a- and b-axis oriented zeolite membranes could be synthesized on the support coated with the monolayer of the seed crystals by secondary growth hydrothermal synthesis. The zeolite membranes prepared were characterized using scanning electron microscope and analyzed by X-ray diffraction.

Keywords:Zeolite Membranes;Anodisc;MFI;Silicalite-1

[References]

Breck DW, “Zeolite Molecular Sieve,”Wiley, New York (1974)
Bein T, Chem. Mater., 8(8), 1636 (1996)
Tavolaro A, Drioli E, Adv. Mater., 11(12), 975 (1999)
Caro J, Noack M, Kolsch P, Schafer R, Microporous Mesoporous Mater., 38(1), 3 (2000)
Noack M, Kolsch P, Toussaint P, Caro J, Chem. Eng. Technol., 25(3), 221 (2002)
Lai Z, Bonilla G, Diaz I, Nery JG, Sujaoti K, Amat MA, Kokkoli E, Terasaki O, Thompson RW, Tsapatsis M, Vlachos DG, Science, 300(5618), 456 (2003)
Lai Z, Tsapatsis M, Nicolich JP, Adv. Funct. Mater., 14(7), 716 (2004)
Zhang FZ, Fuji M, Takahashi M, Chem. Mater., 17(5), 1167 (2005)
Kim HS, Lee SM, Ha K, Jung C, Lee YJ, Chun YS, Kim D, Rhee BK, Yoon KB, J. Am. Chem. Soc., 126(2), 673 (2004)
Chiou YH, Taai TG, Sung SL, Shih HC, Wu CN, Chao KJ, J. Chem. Soc.-Faraday Trans., 92(6), 1061 (1996)
Valtchev V, Mintova S, Konstantinov L, Zeolites, 15(8), 679 (1995)
Valtchev V, Schoeman BJ, Hedlund J, Mintova S, Sterte J, Zeolites, 17(5), 408 (1996)
Valtchev V, Hedlund J, Schoeman BJ, Sterte J, Mintova S, Microporous Materials, 8(1-2), 93 (1997)
Bernal MP, Xomeritakis G, Tsapatsis M, Catal. Today, 67(1-3), 101 (2001)
Lai R, Gavalas GR, Ind. Eng. Chem. Res., 37(11), 4275 (1998)
Larlus O, Valtchev V, Patarin J, Faust AC, Maquin B, Microporous Mesoporous Mater., 56(2), 175 (2002)
Schwanbeck H, Schmidt U, Electrochim. Acta, 45(27), 4389 (2000)
Yang SM, Che KH, Yang YF, Synth. Met., 152(1-3), 65 (2005)
Ha K, Chun YS, Kulak A, Park YS, Lee YJ, Yoon KB, Stud. Surf. Sci. Catal., 135, 3137 (2001)
Lee JS, Ha K, Lee YJ, Yoon, KB, Adv. Mater., 17(7), 837 (2005)
Hedlund J, Jareman F, Curr. Opin. Colloid Interface Sci., 10(5-6), 226 (2005)

[Related Articles]

[1] Breck DW, “Zeolite Molecular Sieve,”Wiley, New York (1974)

[2] Bein T, Chem. Mater., 8(8), 1636 (1996)

[3] Tavolaro A, Drioli E, Adv. Mater., 11(12), 975 (1999)

[4] Caro J, Noack M, Kolsch P, Schafer R, Microporous Mesoporous Mater., 38(1), 3 (2000)

[5] Noack M, Kolsch P, Toussaint P, Caro J, Chem. Eng. Technol., 25(3), 221 (2002)

[6] Lai Z, Bonilla G, Diaz I, Nery JG, Sujaoti K, Amat MA, Kokkoli E, Terasaki O, Thompson RW, Tsapatsis M, Vlachos DG, Science, 300(5618), 456 (2003)

[7] Lai Z, Tsapatsis M, Nicolich JP, Adv. Funct. Mater., 14(7), 716 (2004)

[8] Zhang FZ, Fuji M, Takahashi M, Chem. Mater., 17(5), 1167 (2005)

[9] Kim HS, Lee SM, Ha K, Jung C, Lee YJ, Chun YS, Kim D, Rhee BK, Yoon KB, J. Am. Chem. Soc., 126(2), 673 (2004)

[10] Chiou YH, Taai TG, Sung SL, Shih HC, Wu CN, Chao KJ, J. Chem. Soc.-Faraday Trans., 92(6), 1061 (1996)

[11] Valtchev V, Mintova S, Konstantinov L, Zeolites, 15(8), 679 (1995)

[12] Valtchev V, Schoeman BJ, Hedlund J, Mintova S, Sterte J, Zeolites, 17(5), 408 (1996)

[13] Valtchev V, Hedlund J, Schoeman BJ, Sterte J, Mintova S, Microporous Materials, 8(1-2), 93 (1997)

[14] Bernal MP, Xomeritakis G, Tsapatsis M, Catal. Today, 67(1-3), 101 (2001)

[15] Lai R, Gavalas GR, Ind. Eng. Chem. Res., 37(11), 4275 (1998)

[16] Larlus O, Valtchev V, Patarin J, Faust AC, Maquin B, Microporous Mesoporous Mater., 56(2), 175 (2002)

[17] Schwanbeck H, Schmidt U, Electrochim. Acta, 45(27), 4389 (2000)

[18] Yang SM, Che KH, Yang YF, Synth. Met., 152(1-3), 65 (2005)

[19] Ha K, Chun YS, Kulak A, Park YS, Lee YJ, Yoon KB, Stud. Surf. Sci. Catal., 135, 3137 (2001)

[20] Lee JS, Ha K, Lee YJ, Yoon, KB, Adv. Mater., 17(7), 837 (2005)

[21] Hedlund J, Jareman F, Curr. Opin. Colloid Interface Sci., 10(5-6), 226 (2005)