Ultra-Drawing of Gel Films of Ultra High Molecular Weight Polyethylene/Low Molecular Weight Polymer Blends Containing BaTiO3 Nanoparticles

Ho Sik Park; Jong Hoon Lee; Jae-Do Nam; Soo Jung Seo; Young Kwan Lee; Yong Soo Oh; Hyun-Chul Jung

Macromolecular Research, Vol.14, No.4, 430-437, August, 2006

Ho Sik Park, Jong Hoon Lee, Jae-Do Nam^†, Soo Jung Seo¹, Young Kwan Lee², Yong Soo Oh³, and Hyun-Chul Jung³

Department of Polymer Science and Engineering, Sungkyunkwan Advanced Institute of Nanotechnology (SAINT), Suwon 440-746, Korea
¹Department Metallurgical & Materials Engineering, Sungkyunkwan University, Suwon 440-746, Korea
²Department of Chemical Engineering, Sungkyunkwan University, Suwon 440-746, Korea
³Samsung Electro-Mechanics Co., Ltd., Suwon 443-743, Korea

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The ultra-drawing process of an ultra high molecular weight polyethylene (UHMWPE) gel film was examined by incorporating linear low-density polyethylene (LLDPE) and BaTiO3 nanoparticles. The effects of LLDPE and the draw ratios on the morphological development and mechanical properties of the nanocomposite membrane systems were investigated. By incorporating BaTiO3 nanoparticles in the UHMWPE/LLDPE blend systems, the ultra-drawing process provided a highly extended, fibril structure of UHMWPE chains to form highly porous, composite membranes with well-dispersed nanoparticles. The ultra-drawing process of UHMWPE/LLDPE dry-gel films desirably dispersed the highly loaded BaTiO3 nanoparticles in the porous membrane, which could be used to form multi-layered structures for electronic applications in various embedded, printed circuit board (PCB) systems.

Keywords:ultra high molecular weight polyethylene (UHMWPE);ultra-drawing;gel film;dispersion;porous membrane

[References]

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Smith P, Lemstra PJ, Booij HC, J. Polym. Sci. B: Polym. Phys., 19, 877 (1981)
Matsuo M, Manley RS, Macromolecules, 15, 985 (1982)
Matsuo M, Manley RS, Macromolecules, 16, 1505 (1983)
Sawatari C, Okumura T, Matsuo M, Polymer, 18, 741 (1986)
Kanamoto T, Tsuruta A, Tanaka K, Takeda M, Poter RS, Polymer, 15, 327 (1983)
Kanamoto T, Tsuruta A, Tanaka K, Takeda M, Porter RS, Macromolecules, 21, 470 (1988)
Uehara H, Nakae M, Kanamoto T, Zachariades AE, Porter RS, Macromolecules, 32(8), 2761 (1999)
Yang DH, Yoon GH, Shin GJ, Kim SH, Rhee JM, Khang G, Lee HB, Macromol. Res., 13(2), 120 (2005)
Karay G, Bevis MJ, J. Polym. Sci. B: Polym. Phys., 35, 263 (1997)
Smith P, Lemstra PJ, J. Colloid Polym. Sci., 258, 89 (1980)
Kanamoto T, Tsuruta A, Tanaka M, Porter RS, Polym. J., 15, 327 (1983)
Kanamoto T, Kiyooka S, Tovmasyan Y, Sano H, Narukawa H, Polymer, 31, 2039 (1990)
Han SS, Yoon WS, Choi JH, Kim SY, Lyoo WS, J. Appl. Polym. Sci., 66, 1583 (1977)
Lyoo WS, Han SS, Choi JH, Cho YW, Ha WS, J. Korean Fib. Soc., 32, 1023 (1995)
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Matsuo M, Kitayama C, Polymer, 17, 479 (1985)

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[2] Smith P, Lemstra PJ, Booij HC, J. Polym. Sci. B: Polym. Phys., 19, 877 (1981)

[3] Matsuo M, Manley RS, Macromolecules, 15, 985 (1982)

[4] Matsuo M, Manley RS, Macromolecules, 16, 1505 (1983)

[5] Sawatari C, Okumura T, Matsuo M, Polymer, 18, 741 (1986)

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[7] Kanamoto T, Tsuruta A, Tanaka K, Takeda M, Porter RS, Macromolecules, 21, 470 (1988)

[8] Uehara H, Nakae M, Kanamoto T, Zachariades AE, Porter RS, Macromolecules, 32(8), 2761 (1999)

[9] Yang DH, Yoon GH, Shin GJ, Kim SH, Rhee JM, Khang G, Lee HB, Macromol. Res., 13(2), 120 (2005)

[10] Karay G, Bevis MJ, J. Polym. Sci. B: Polym. Phys., 35, 263 (1997)

[11] Smith P, Lemstra PJ, J. Colloid Polym. Sci., 258, 89 (1980)

[12] Kanamoto T, Tsuruta A, Tanaka M, Porter RS, Polym. J., 15, 327 (1983)

[13] Kanamoto T, Kiyooka S, Tovmasyan Y, Sano H, Narukawa H, Polymer, 31, 2039 (1990)

[14] Han SS, Yoon WS, Choi JH, Kim SY, Lyoo WS, J. Appl. Polym. Sci., 66, 1583 (1977)

[15] Lyoo WS, Han SS, Choi JH, Cho YW, Ha WS, J. Korean Fib. Soc., 32, 1023 (1995)

[16] Kunugi T, Akiyama I, Polymer, 23, 1199 (1982)

[17] Garrett PD, Grubb DT, Polym. Commun., 29, 60 (1988)

[18] Kunugi T, Kawasumi T, Ito TJ, J. Appl. Polym. Sci., 40, 2101 (1990)

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[20] Hallam MA, Cansfield DLM, Ward IM, Pollard G, J. Mater. Sci., 21, 4199 (1986)

[21] Bastiaansen CWM, J. Polym. Sci. B: Polym. Phys., 28, 1457 (1990)

[22] Liu BL, Murakami N, Sumita M, Kiyasaka K, J. Polym. Sci. B: Polym. Phys., 27, 2441 (1989)

[23] Ogita T, Suzuki N, Kawahara Y, Polymer, 33, 698 (1992)

[24] Ogita T, Kawahara Y, Soga Y, Matsuo M, Colloid Polym. Sci., 270, 833 (1992)

[25] Nunes RW, Marhn JR, Johnson JF, Polym. Eng. Sci., 22, 205 (1982)

[26] Douglas MJF, Freed F, Macromolecules, 16, 741 (1983)

[27] Yeh J, Wu H, Polymer, 30, 1 (1998)

[28] Mihailov M, Minkova L, Colloid Polym. Sci., 265, 681 (1987)

[29] Sawatari C, Matsuo M, Polymer, 30, 1603 (1989)

[30] Bin Y, Fukuda M, Kurosu H, Matsuo M, Macromol. Symp., 141, 1 (2000)

[31] Yeh JT, Lin YL, Fan-Chiang CC, Macromol. Chem. Phys., 197, 3531 (1996)

[32] Yeh JT, Chang SS, Yen MS, J. Appl. Polym. Sci., 70(1), 149 (1998)

[33] Nakajima N, Ibata J, Jpn. Pats., 57,177,035 (1983)

[34] Simeonov I, Nililova Z, Komitov P, Naidenova K, Bulg. Pat., 31, 868 (1982)

[35] Datta M, Osaka T, Schultze JW, Microelectronic Packaging, CRC Press, New York (2004)

[36] Tummala RR, Fundamentals of Microsystems Packaging, McGraw-Hill, New York (2001)

[37] Ohta T, Takada A, Yamamura T, Kawaguchi A, Murakami S, Polymer, 36(11), 2181 (1995)

[38] Sakami H, Izushi T, Iida S, Kobunshi Ronbunshu, 38, 103 (1981)

[39] Sakami H, Iida S, Sasaki K, Kobunshi Ronbunshu, 36, 36 (1979)

[40] Sakai Y, Miyasaka K, Polymer, 29, 1608 (1988)

[41] Darras D, Sequela R, Rietsch F, J. Polym. Sci. B: Polym. Phys., 30, 349 (1992)

[42] Ogita T, Yamamoto R, Suzuki N, Ozaki F, Matsuo M, Polymer, 32, 822 (1991)

[43] Matsuo M, Kitayama C, Polymer, 17, 479 (1985)