2- and 3-dimensional colloid arrays were fabricated using highly-charged and monodisperse Poly(Styrene/Sodium Styrene Sulfonate) particles with 3-aminopropyl trimethoxysilane (APTMS)-modified glass substrate. The colloid arrays were formed under natural convection drying at room temperature. The 3-dimensional arrays on the APTMS-modified glass substrate showed denser packing pattern with no crevices, as compared with that of cleaned bare glass substrate. Hyperdesne and square lattice-free array can be explained by a stronger capillary force due to the hydrated and hairy surfaces at the water miniscus, and which leaded to substantial particle deformation and hexagonal close packing.