Journal of Chemical Thermodynamics, Vol.38, No.4, 418-426, 2006
Partial molar volumes of organic solutes in water. XIII. Butanols (aq) at temperatures T=298 K to 573 K and at pressures up to 30 MPa
Density data for dilute aqueous solutions of 1-butanol, 2-butanol, 2-methyl-1-propanol (iso-butanol), and 2-methyl-2-propanol (tert-butanol) are presented together with partial molar volumes at infinite dilution calculated from the experimental data. The measurements were performed at temperatures from T = 298.15 K up to T = 573.15 K and at pressure close to the saturated vapour pressure of water, at pressures close to p = 20 MPa and p = 30 MPa. The data were obtained using a high-temperature high-pressure flow vibrating-tube densimeter. (C) 2005 Elsevier Ltd. All rights reserved.
Keywords:density;partial molar volume;aqueous alcohols;1-butanol;2-butanol;2-methyl-2-propanol;2-methyl-2-propanol;high temperature;high pressure