Phase changes in Lennard-Jones (LJ) clusters containing between 74 and 78 atoms are investigated by means of exchange Monte Carlo simulations in the canonical ensemble. The replica temperatures are self-adapted to facilitate the convergence. Although the 74- and 78-atom clusters have icosahedral global minima, the clusters with 75-77 atoms have decahedral ground-state structures and they undergo a structural transition to icosahedral minima before melting. The structural transitions are characterized by quenching and by looking at the Q(4) and Q(6) orientational bond order parameters. The transition temperatures are estimated to be 0.114, 0.065, and 0.074 reduced units for LJ(75), LJ(76), and LJ(77), respectively. These values, their ordering and the associated latent heats are compared with other estimates based on the harmonic superposition approach.