Langmuir, Vol.22, No.11, 4914-4916, 2006
Two-dimensional fluidics based on differential lyophobicity and gravity
We have prepared planar fluidics devices using binary chemical patterns consisting of hydrophobic "roads" on which water droplets slide easily and more hydrophobic "curbs" that direct droplet motion. Contact angle and contact angle hysteresis both control the motion of liquid droplets on surfaces. The difference between the advancing contact angles of the two regions prevents the liquid from crossing the interface between them. The low hysteresis of the roads allows facile movement. Gravity (slight tilting of samples) forces droplets to move effortlessly in defined pathways even though the difference in contact angles is not large and both regions are hydrophobic.