화학공학소재연구정보센터
Journal of Applied Electrochemistry, Vol.36, No.8, 883-888, 2006
Preparation of Ir0.3Sn(0.7-x)TixO2 electrodes by the polymeric precursor method: Characterization and lifetime study
Thin film electrodes of nominal composition Ir0.3Sn(0.7-x)Ti (x) O-2 (0 <= x <= 0.7) were prepared by decomposition of polymeric precursors. The solutions used to prepare the electrodes were obtained by mixing of the precursor salts with a mixture of ethylene glicol and citric acid. The films were burned at 400 degrees C and characterized by X-ray diffraction, scanning electronic microscopy, energy dispersive X-ray spectroscopy and cyclic voltammetry. The electrodes were submitted to high anodic current density in order to evaluate their lifetime in perchloric acid solution. Results show that the electrodes present compositions similar to that of the precursor solutions, suggesting that there is no loss of tin during the calcination step. The electrodes had large surface area and higher lifetime in comparison with electrodes of similar composition prepared by other methods. The possible mechanisms involved in deactivation of the electrodes are discussed.