Characterization of the bis-silylated endofullerene Sc3N@C-80

Wakahara T; Iiduka Y; Ikenaga O; Nakahodo T; Sakuraba A; Tsuchiya T; Maeda Y; Kako M; Akasaka T; Yoza K; Horn E; Mizorogi N; Nagase S

Journal of the American Chemical Society, Vol.128, No.30, 9919-9925, 2006

Wakahara T, Iiduka Y, Ikenaga O, Nakahodo T, Sakuraba A, Tsuchiya T, Maeda Y, Kako M, Akasaka T, Yoza K, Horn E, Mizorogi N, Nagase S

The photochemical reaction of Sc3N@C-80 with 1,1,2,2-tetramesityl-1,2-disilirane affords the adduct as a bis-silylated product. The adduct was characterized by NMR spectroscopy and single-crystal X-ray structure analysis. The dynamic behavior of the disilirane moiety and the encapsulated Sc3N cluster were also investigated. The unique redox property of the adduct is reported by means of CV and DPV. Experimental results were confirmed by density functional calculations.