NaCl-type frameworks of [M(pyrazine)(2)NO2]ClO4 (M) Co, Cu), the first examples containing mu 1,3-nitrito bridges showing antiferromagnetism

Liu T; Chen YH; Zhang YJ; Wang ZM; Gao S

Inorganic Chemistry, Vol.45, No.23, 9148-9150, 2006

Liu T, Chen YH, Zhang YJ, Wang ZM, Gao S

Two new 3D NaCl-type frameworks of [M(pyrazine)(2)NO2]ClO4 (M = Co, Cu), consist of (4, 4) sheets of metal-pyrazine connected by mu(1,3)-nitrito, representing the first examples of mu(1,3)-nitrito bridges and exhibiting antiferromagnetism.