Cobalt silicate hydroxide (Co-3 [Si2O5](2) [OH](2)) was prepared by chemical method for use in electrochemical capacitors. X-ray diffraction (XRD) and transmission electron microscopy (TEM) tests indicate that the material was pure hexagonal phase with uniform nanometer size distribution. Cyclic voltammeter (CV) and galvanostatic charge/discharge measurements show that the cobalt silicate hydroxide-based electrode has stable electrochemical capacitor proper-ties between potential range of 0.1-0.55 V with a maximum specific capacitance of 237 F g(-1) in alkaline solution and 95% of capacity efficiency was reached after 150 cycles. Electrochemical impedance spectra (EIS) investigation illustrates that the capacitance of the test electrode was mainly consisted of pseudo-capacitance, which was caused by underpotential deposition of H3O+ at the electrode surface. (c) 2006 Published by Elsevier B.V.