화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.24, No.1, 1-10, January, 2007
DOI10.1007/s11814-007-5001-8  Export Citation
Prediction of thermal conductivities of oxygen, nitrogen and carbon dioxide at the moderate density regime via semi-empirical assessment
Behzad Haghighi†, Daruish Shahidi, Mohammad Mehdi Papari1, and Mohsen Najafi2
  • Thermodynamic and Transport Properties Research Laboratory (T&TPRL), Department of Chemistry, University of Birjand, Postal Code 97175-615, Birjand, Southern Khorasan Province, Iran
  • 1Chemistry Department, Shiraz University of Technology, Shiraz, Fars Province, 71555-313, Iran
  • 2Atomic Energy Organization of Iran (AEOI), Tehran, Tehran Province, Iran
E-mail:
Thermal conductivities coefficients for gaseous state of N2, O2 and CO2 at zero density are determined by the inversion technique. The Lennard-Jones 12-6 (LJ 12-6) potential energy function is used as the initial model potential required by the technique. The Wang Chang-Uhlenbeck-de Boer (WCUB) approach of the kinetic theory of gases has been used for calculating the contribution of molecular degree of freedom to the thermal conductivity of N2, O2 and CO2. Also, the initial density dependence of gaseous thermal conductivity according to the Rainwater-Friend theory, which was given by Najafi et al., has been considered for N2, O2 and CO2.
Keywords:Kinetic Theory of Gases;Initial Density Dependence;Thermal Conductivity;Molecular Degree of Freedom;Interaction Potential;Collision Integrals;Direct Inversion Method
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