The Fe-doped Li3V2(PO4)(3) cathode materials for Li-ion batteries were synthesized by a conventional solid-state reaction, and the Fe-doping effects on the Li electrochemical extraction/insertion performance of Li3V2(PO4)(3) were investigated by galvanostatic charge/discharge and cyclic voltammetry measurements. The optimal Fe-doping content x is 0.02-0.04 in Li3FexV2-x(PO4)(3) system. The Fe-doped Li3V2(PO4)(3) samples showed a better cyclic ability between 3.0 and 4.9 V, for example, the discharge capacity of Li3Fe0.02V1.98(PO4)(3) was 177 mAh g(-1) in the 1st cycle and 126 mAh g(-1) in the 80th cycle. The retention rate of discharge capacity is about 71%, much higher than 58% of the undoped system. The improved electrochemical performances of the Li3V2(PO4)(3) could be attributed to the increased electrical conductivity and structural stability deriving from the incorporation of the Fe3+ ions. (c) 2006 Published by Elsevier B.V.