화학공학소재연구정보센터
Langmuir, Vol.22, No.26, 11016-11021, 2006
Tuning rheochaos by temperature in wormlike micelles
We investigate the critical role played by the mean micellar length during the route to rheochaos for wormlike micellar gels of surfactant cetyltrimethylammonium tosylate in the presence of salt sodium chloride that show coupling of flow to concentration fluctuations. To this end, we have carried out stress/shear rate relaxation experiments at a fixed shear rate/stress but at different temperatures to take the sample through the route to rheochaos. We see the type-II intermittency route to rheochaos in stress relaxation measurements and the type-III intermittency route to rheochaos in shear rate relaxation measurements. We have also carried out linear rheology measurements at different temperatures to estimate the mean micellar length (L) over bar, the reptation time tau(rep), and the breaking time tau(break). It is shown that (L) over bar changes by approximate to 58%, as the sample goes through the route to rheochaos.