화학공학소재연구정보센터
Thin Solid Films, Vol.515, No.3, 1223-1227, 2006
The structure of Ta nanopillars grown by glancing angle deposition
Regular arrays of Ta nanopillars, 200 nm wide and 500 nm tall, were grown on SiO2 nanosphere patterns by glancing angle sputter deposition (GLAD). Plan-view and cross-sectional scanning electron microscopy analyses show dramatic changes in the structure and morphology of individual nanopillars as a function of growth temperature T, ranging from 200 to 700 degrees C. At low temperatures, T-s <= 300 degrees C, single nanopillars develop on each sphere and branch into subpillars near the pillar top. In contrast, T-s >= 500 degrees C leads to branching during the nucleation stage at the pillar bottom. The top branching at low Ts is associated with surface mounds on a growing pillar that, due to atomic shadowing, develop into separated subpillars. At high Ts, the branching occurs during the nucleation stage where multiple nuclei on a single SiO2 sphere develop into subpillars during a competitive growth mode which, in turn, leads to intercolumnar competition and the extinction of some nanopillars. (c) 2006 Elsevier B.V. All rights reserved.