화학공학소재연구정보센터
Journal of Non-Newtonian Fluid Mechanics, Vol.139, No.3, 209-213, 2006
Thermodynamic admissibility of the extended Pom-Pom model for branched polymers
The thermodynamic consistency of the eXtended Pom-Pom (XPP) model for branched polymers of Verbeeten et al. [W.M.H. Verbeeten, G.W.M. Peters, F.P.T. Baaijens, Differential constitutive equations for polymer melts: the extended pom-pom model, J. Rheol. 45 (4) (2001) 823-843; W.M.H. Verbeeten, G.W.M. Peters, F.P.T. Baaijens, Differential constitutive equations for polymer melts: the extended pom-pom model (vol 45, pg 823-843, 2001), J. Rheol. 45 (6) (2001) 1489] as well as its modified version [J. van Meerveld, Note on the thermodynamic consistency of the integral pompom model, J. Non-Newtonian Fluid Mech. 108 (1-3) (2002) 291-299] is investigated from the perspective of non-equilibrium thermodynamics, namely the General Equation for Non-Equilibrium Reversible-Irreversible Coupling (GENERIC) framework. The thermodynamic admissibility of the XPP model is shown for both its original and modified form. According to the GENERIC formalism, the parameter C( introduced by Verbeeten et al. to predict non-zero second normal stress in shear flows must fulfill the condition 0 <= alpha <= 1. (c) 2006 Elsevier B.V. All rights reserved.