A change in the surface energy and surface resistivity of a thin film of polypropylene (PP) of thickness 100 Pm was investigated, using direct current (DC) glow discharge. The thin film of the PP was treated for various discharge powers and treatment time and the modification in the surface energy and the surface resistivity was observed. To investigate the modification in the surface energy after DC glow discharge treatment, contact angle of two test liquids formamide and de-ionized water over the surface of PP film was measured. By measuring the contact angle the change in surface energy and its two polar and dispersive components have been measured. It was observed that at a given power level of DC glow discharge surface energy and its polar component increases with increase of the treatment time, attains a maximum value, and then becomes almost constant. Correspondingly, with increase in surface energy, a decrease in surface resistivity was observed. Also, a change in surface morphology was observed by atomic force microscopy and by FT-IR spectra generation of polar groups at the surface of PP film. (c) 2007 Wiley Periodicals, Inc.