화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.129, No.11, 3062-3062, 2007
Defect-site promoted surface reorganization in nanocrystalline ceria for the low-temperature activation of ethylbenzene
Defect-site enriched nanocrystalline ceria prepared by an alcoholysis method favors oxidative dehydrogenation of ethylbenzene using nitrous oxide with high conversion and selectivity at much lower temperatures compared to ceria samples prepared by other conventional methods. A direct correlation exists between the concentration of -Ce4+-O--Ce3+-type defect sites and the reaction rates and, hence, the activation temperature required for the reaction.