Polymer, Vol.48, No.5, 1352-1359, 2007
A law controlling polymer recrystallization showing up in experiments on s-polypropylene
When polymers are crystallized at large supercoolings a subsequent heating is accompanied by recrystallization processes, which proceed to a fixed final melting point. We studied these processes with small-angle X-ray scattering and DSC measurements for three s-polypropylenes with different stereoregularities and co-unit contents. As is known from previous experiments, crystal thicknesses d(c) depend on the crystallization temperature T-c only, being not affected by stereo defects or co-units. The new experiments, all carried out at low crystallization temperatures, again confirm this property; in plots of d(c)(-1) versus T, all points are located on a unique straight crystallization line. A similarly simple law controls the crystal thickness during the continuous structure reorganization on heating. Over an extended temperature range d(c)(-1) changes linearly with temperature, guided by a unique, i.e., sample-invariant, 'recrystallization line'. Crystallization and recrystallization lines extrapolate for d(c)(-1) -> 0 to the same limiting temperature, T-c(infinity) and differ only in slope. The findings indicate that both the initial crystallization at T-c and the process of recrystallization use a pathway via a transient mesomorphic phase. The DSC thermograms of the samples show a multiple peak structure which varies with the heating rate. The SAXS results enable the peaks to be assigned to different melting processes. (c) 2007 Elsevier Ltd. All rights reserved.