Fabrication of silver nanoparticles via self-regulated reduction by 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate

Sukjeong Choi; Ki-Sub Kim; Sun-Hwa Yeon; Jong-Ho Cha; Huen Lee; Chang-Jin Kim; Ick-Dong Yoo

Korean Journal of Chemical Engineering, Vol.24, No.5, 856-859, September, 2007

DOI10.1007/s11814-007-0054-2 Export Citation

Fabrication of silver nanoparticles via self-regulated reduction by 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate

Sukjeong Choi, Ki-Sub Kim, Sun-Hwa Yeon, Jong-Ho Cha, Huen Lee^†, Chang-Jin Kim¹, and Ick-Dong Yoo¹

Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701, Korea
¹Antioxidant Research Lab., Korea Research Institute of Bioscience and Biotechnology, 52 Oeun-dong, Yuseong-gu, Daejeon 305-333, Korea

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Silver nanoparticles exhibiting antimicrobial properties via self-regulated reduction were successfully prepared by using hydroxylated ionic liquids in an aqueous phase without additives. A new water-phase synthesis of silver nanoparticles using 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate ([HEMIm][BF4]) and 1-(2'-hydroxyethyl)-2-methyl-3-dodecylimidazolium chloride ([C12HEMIm][Cl]) was described. 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate serves as both a reductant and a stabilizer in this fabrication. Furthermore, we presented the antimicrobial properties of the resulting silver nanoparticles through the minimal inhibitory concentrations (MIC) test.

Keywords:Ionic Liquid;Silver Nanoparticles;Antimicrobial Properties

[References]

Kim KS, Choi S, Demberelnyamba D, Lee H, Oh J, Lee BB, Mun SJ, Chem. Commun., 828 (2004)
MacFarlane DR, Huang J, Forsyth M, Nature, 402, 792 (1999)
Dupont J, Fonseca GS, Umpierre AP, Fichtner PFP, Teixeira SR, J. Am. Chem. Soc., 124(16), 4228 (2002)
Kim KS, Demberelnyamba D, Lee H, Langmuir, 20(3), 556 (2004)
Kim KS, Demberelnyamba ND, Yeon SW, Choi S, Cha JH, Lee H, Korean J. Chem. Eng., 22(5), 717 (2005)
Toshima N, Yonezawa T, New J. Chem., 1179 (1998)
Lee CL, Wan CC, Wang YY, Adv. Funct. Mater., 344 (2001)
Demberelnyamba D, Kim KS, Choi S, Park SY, Lee H, Kim CJ, Yoo ID, Bioorg. Med. Chem., 12, 853 (2004)
Yeon SH, Kim KS, Choi S, Cha JH, Lee H, JPCB, 109, 17928 (2005)
Choi S, Kim KS, Lee H, Oh JS, Lee BB, Korean J. Chem. Eng., 22(2), 281 (2005)
Pernak J, Sobaszkiewica K, Mirska I, Green Chem., 5, 52 (2003)
Toshima N, Yonezawa T, New J. Chem., 1179 (1998)
Teranishi T, Hosoe M, Tanaka T, Miyake M, J. Phys. Chem. B, 103(19), 3818 (1999)
Cournoyer JJ, Kshirsagar T, Fantauzzi PP, Figliozzi GM, Makdessian T, Yan B, J. Comb. Chem., 4, 120 (2002)
Hopps HB, Aldrichimica Acta, 33, 28 (2000)

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[Related Articles]

[1] Kim KS, Choi S, Demberelnyamba D, Lee H, Oh J, Lee BB, Mun SJ, Chem. Commun., 828 (2004)

[2] MacFarlane DR, Huang J, Forsyth M, Nature, 402, 792 (1999)

[3] Dupont J, Fonseca GS, Umpierre AP, Fichtner PFP, Teixeira SR, J. Am. Chem. Soc., 124(16), 4228 (2002)

[4] Kim KS, Demberelnyamba D, Lee H, Langmuir, 20(3), 556 (2004)

[5] Kim KS, Demberelnyamba ND, Yeon SW, Choi S, Cha JH, Lee H, Korean J. Chem. Eng., 22(5), 717 (2005)

[6] Toshima N, Yonezawa T, New J. Chem., 1179 (1998)

[7] Lee CL, Wan CC, Wang YY, Adv. Funct. Mater., 344 (2001)

[8] Demberelnyamba D, Kim KS, Choi S, Park SY, Lee H, Kim CJ, Yoo ID, Bioorg. Med. Chem., 12, 853 (2004)

[9] Yeon SH, Kim KS, Choi S, Cha JH, Lee H, JPCB, 109, 17928 (2005)

[10] Choi S, Kim KS, Lee H, Oh JS, Lee BB, Korean J. Chem. Eng., 22(2), 281 (2005)

[11] Pernak J, Sobaszkiewica K, Mirska I, Green Chem., 5, 52 (2003)

[12] Toshima N, Yonezawa T, New J. Chem., 1179 (1998)

[13] Teranishi T, Hosoe M, Tanaka T, Miyake M, J. Phys. Chem. B, 103(19), 3818 (1999)

[14] Cournoyer JJ, Kshirsagar T, Fantauzzi PP, Figliozzi GM, Makdessian T, Yan B, J. Comb. Chem., 4, 120 (2002)

[15] Hopps HB, Aldrichimica Acta, 33, 28 (2000)