화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.24, No.5, 877-880, September, 2007
Comparison of YAG: Eu phosphors synthesized by supercritical water in batch and continuous reactors
E-mail:
Luminescent yttrium aluminum garnet (YAG, Y3Al5O12) nanoparticles doped with Eu (10 at%) were synthesized in batch-type and continuous-type supercritical water (SCW) reactors. In the case of the continuous-type SCW method, the particles of YAG : Eu phosphors were much smaller and demonstrated a uniform spherical-like shape. Inversely, in the case of the batch-type SCW method, a needle-like or elliptical-like shape was formed because a finite amount of time was required to reach SCW conditions from ambient conditions. However, the emission intensity of YAG : Eu phosphors synthesized by using the batch-type SCW method was stronger. Therefore, it is concluded that the continuous-type SCW method is superior to the batch-type SCW method from the viewpoint of the particle size and shape, but the luminescence property of phosphors in the continuous-type SCW method needs to be improved. In addition, a calcination process slightly improved the luminescence intensities of YAG : Eu phosphors generated by using either the batch-type or continuous-type SCW methods.
  1. Kang YC, Lenggoro IW, Park SB, Okuyama K, J. Phys. Chem. Solids, 60, 1855 (1999)
  2. Lopez OA, McKittrick J, Shea LE, J. Lumines., 71, 1 (1997)
  3. Abell JS, Harris IR, Cockayne B, Lent B, J. Mater. Sci., 9, 527 (1974)
  4. Hakuta Y, Haganuma T, Sue K, Adschiri T, Arai K, Mater. Res. Bull., 38, 1257 (2003)
  5. Gowada G, J. Mater. Sci. Lett., 5, 1029 (1986)
  6. Hay RS, J. Mater. Res., 8, 578 (1993)
  7. Nyman M, Caruso J, Hampden-Smith MJ, J. Am. Ceram. Soc., 80, 1231 (1997)
  8. Jung KY, Lee DY, Kang YC, Park SB, Korean J. Chem. Eng., 21(5), 1072 (2004)
  9. Shea LE, McKittrick J, Lopez OA, Sluzky E, J. Am. Ceram. Soc., 79, 3257 (1996)
  10. Shikao S, Jiye W, J. Alloy. Compd., 327, 82 (2001)
  11. Zhou Y, Lin J, Yu M, Wang S, J. Alloy. Compd., 375, 93 (2004)
  12. Lee HC, In JH, Hwang KY, Lee CH, Ind. Eng. Chem. Res., 43(13), 3223 (2004)
  13. Adschiri T, Hakuta Y, Arai K, Ind. Eng. Chem. Res., 39(12), 4901 (2000)
  14. Nam SC, Kim GJ, Korean J. Chem. Eng., 21(3), 582 (2004)
  15. Yoon MJ, In JH, Lee HC, Lee CH, Korean J. Chem. Eng., 23(5), 842 (2006)
  16. In JH, Lee HC, Yoon MJ, Lee KK, Lee JW, Lee CH, J. Supercrit. Fluids, 40, 389 (2007)
  17. Hsu WT, Wu WH, Lu CH, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 104, 40 (2003)
  18. Vecht A, Gibbons C, Davies D, Jing XP, Marsh P, Ireland T, Silver J, Newport A, Barber D, J. Vac. Sci. Technol. B, 17, 750 (1999)
  19. He C, Guan Y, Yao L, Cai W, Li X, Yao Z, Mater. Res. Bull., 38, 973 (2003)